The ten elements from yttrium to cadmium (Z=39 to 48) constitute the second transition series.
In yttrium, 4d subshell begins filling up and its outer electronic configuration is 4d1 5s2.
The filling up of the 4d orbitals continues as we keep moving in this period towards the next nine elements, namely, zirconium(Z=40) niobium(Z=41), molybdenum(Z=42), technetium(Z=43), ruthenium(Z=44), rhodium(Z=45), palladium(Z=46), silver(Z=47), and cadmium(Z=48).
In cadmium(Z=48) the 4d subshell has now the maximum permissible number of 10 electrons, the configuration of the outer shell being 4d10 5s2.
According to the definition of d block elements already given, the nine elements from Y to Ag, may be taken as constituting the Second series of d block elements.
The definition, based on the number of electron in the 4d subshell excludes Cd from second transition series.
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