What is inner transition elements? what is lanthanoid series?
·
The f block elements are those which have partly
filled f subshells of the third to the outermost (antepenultimate),
·
(n-2)th energy shells in their elementary or
ionic state.
·
These elements are also called inner transition
elements and are divided into two series.
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(i) The
Lanthanoid series,
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(ii) The Actinoid series
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In Lanthanoids, it is the 4f subshell which is being successively filled while in actinoids,
it is the 5f subshell which is being
successively filled.
THE LANTHANOID SERIES:
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Lanthanum (Z=57) and the next fourteen elements
(Z= 58-71) which follow it are called Lanthanoids or l lanthanum lanthanones.
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These fifteen elements closely resemble one
another and form a distinct group with lanthanum as the prototype; hence the
name lanthanoids or lanthanones.
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The reason why they resemble lanthanum so
closely lies in their electronic configurations.
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The configuration of lanthanum is [Xe] 5d16s2.
·
In the succeeding fourteen elements, 14
electrons are successively added to the empty 4f subshell of the lanthanum configuration.
·
Thus, while in cerium the element immediately following
lanthanum, one 4f electron is added
to the lanthanum configuration.
·
Hence, the last element of the series, fourteen
4f electrons is added to the
lanthanum configuration.
Hence, the configuration of cerium and lutetium
are [Xe] 4f15d16s2 and [Xe] 4f145d16s2 respectively.
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